Lovelace's Square - Designed Fluorescence EEM Data for Second-Order Calibration
CC-BY-4.0 | v1.0 | 2026-02-21
Designed Fluorescence EEM Data for Second-Order Calibration
SpectroscopyFluorescence
Authors
Åsmund Rinnan; Jordi Riu
Affiliations
1Royal Veterinary and Agricultural University (KVL), Denmark; Universitat Rovira i Virgili, Spain
Fluorescence excitation-emission matrix (EEM) measurements of 405 laboratory-prepared samples containing known mixtures of catechol, hydroquinone, indole, resorcinol, tryptophane, and tyrosine. The main fluorescence array is arranged as sample x emission x excitation x replicate with shape 405 x 136 x 19 x 5, and the concentration matrix has shape 405 x 6. The source documentation describes 12 experimental dataset groups within the same arrays; the dataset number for each sample is stored in the MATLAB metadata field fluor.class{1,1,2}. Measurements were acquired on a Varian Eclipse Fluorescence Spectrometer. The source page states that the samples were generated and measured by Åsmund Rinnan and Jordi Riu.
Reference
Rinnan, Å. Application of PARAFAC on Spectral Data. PhD thesis, Royal Veterinary and Agricultural University, Denmark, 2004.
Bro, R.; Rinnan, Å.; Faber, N.M. (2005). Standard error of prediction for multilinear PLS: 2. Practical implementation in fluorescence spectroscopy. Chemometrics and Intelligent Laboratory Systems, 75(1), 69-76. https://doi.org/10.1016/j.chemolab.2004.04.014
24
3
Comments (0)
No comments yet. Be the first to share your thoughts.